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The first free N-heterocyclic carbene (NHC) stable in liquid water, thereby validating Breslow’s 67-year-old hypothesis, has been reported in Science Advances (https://ccdc-info.com/44SAAwo). CSD Entry SUZJEG reveals how steric shielding from chlorinated carborane clusters protects the reactive carbene centre. 🔗 https://ccdc-info.com/4jtAX49 #FeaturedStructureFriday #Crystallography | Cambridge Crystallographic Data Centre (CCDC)
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